Oxygen isotope speedometry in granulite facies garnet recording fluid/melt–rock interaction (Sør Rondane Mountains,East Antarctica)     

Fumiko Higashino  Daniela Rubatto  Tetsuo Kawakami  Anne‐Sophie Bouvier  Lukas P. Baumgartner 《Journal of Metamorphic Geology》2019,37(7):1037-1048

In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ¹⁸O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ¹⁸O = ~15‰) to the rim (δ¹⁸O = ~11‰) suggests that the ¹⁸O/¹⁶O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the ¹⁸O/¹⁶O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ¹⁸O value of the garnet rim, together with the previously reported low δ¹⁸O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ¹⁸O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.  相似文献   

Controls on metamorphic equilibration: the importance of intergranular solubilities mediated by fluid composition          下载免费PDF全文

W. D. Carlson  J. D. Hixon  J. M. Garber  R. J. Bodnar 《Journal of Metamorphic Geology》2015,33(2):123-146

A dramatic demonstration of the role of intergranular solubility in promoting chemical equilibration during metamorphism is found in the unusual zoning of garnet in pelitic schist exposed at Harpswell Neck, Maine, USA. Many garnet crystals have irregular, patchy distributions of Mn, Cr, Fe and Mg in their inclusion‐rich interiors, transitioning to smooth, concentric zoning in their inclusion‐poor outer rims; in contrast, zoning of Ca and Y is comparatively smooth and concentric throughout. We re‐assess the disputed origin of these zoning features by examining garnet growth in the context of the thermal and structural history of the rocks, and by evaluating the record of fluid–rock interaction revealed in outcrop‐scale veining and fluid‐inclusion assemblages. The transition in the character of garnet zoning correlates with the onset of a synkinematic, simple‐shear‐dominated phase of garnet growth and with a shift in the composition of the intergranular fluid from CO₂‐rich to H₂O‐rich. Compositional variations in garnet are therefore best explained by a two‐stage growth history in which intergranular diffusive fluxes reflect differences in the concentration of dissolved species in these two contrasting fluids. Interiors of garnet crystals grew in the presence of a CO₂‐rich fluid, in which limited solubility for Mn and Cr (and perhaps Fe and Mg) produced patchy disequilibrium overprint zoning, while appreciable solubility for Ca and Y permitted their rock‐wide equilibration. Rims grew in the presence of an H₂O‐rich fluid, in which high intergranular concentrations for all elements except Cr enabled diffusion over length scales sufficient for rock‐wide equilibration. This striking example of partial chemical equilibrium during reaction and porphyroblast growth implies that thermal effects may commonly be subsidiary in importance to solubilities in the intergranular medium as determinants of length scales for metamorphic equilibration.  相似文献   

Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration          下载免费PDF全文

Tim J. Dempster  Shona Symon  Peter Chung 《Journal of Metamorphic Geology》2017,35(6):585-600

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.  相似文献   

A discontinuous finite element suspended sediment transport model for water quality assessments in river networks          下载免费PDF全文

Fabricio Fiengo Pérez  Lieve Sweeck  Marc Elskens  Willy Bauwens 《水文研究》2017,31(9):1804-1816

Suspended sediment plays an important role in the distribution and transport of many pollutants (such as radionuclides) in rivers. Pollutants may adsorb on fine suspended particles (e.g. clay) and spread according to the suspended sediment movement. Hence, the simulation of the suspended sediment mechanism is indispensable for realistic transport modelling. This paper presents and tests a simple mathematical model for predicting the suspended sediment transport in river networks. The model is based on the van Rijn suspended load formula and the advection–diffusion equation with a source or sink term that represents the erosion or deposition fluxes. The transport equation is solved numerically with the discontinuous finite element method. The model evaluation was performed in two steps, first by comparing model simulations with the measured suspended sediment concentrations in the Grote Nete–Molse Nete River in Belgium, and second by a model intercomparison with the sediment transport model NST MIKE 11. The simulations reflect the measurements with a Nash‐Sutcliffe model efficiency of 0.6, while the efficiency between the proposed model and the NST MIKE 11 simulations is 0.96. Both evaluations indicate that the proposed sediment transport model, that is sufficiently simple to be practical, is providing realistic results.  相似文献   

Analytical solutions for advective–dispersive solute transport in double‐layered finite porous media     

Peter John Cleall 《国际地质力学数值与分析法杂志》2011,35(4):438-460

Analytical solutions for advection and dispersion of a conservative solute in a one‐dimensional double‐layered finite porous media are presented. The solutions are applicable to five scenarios that have various combinations of fixed concentration, fixed flux and zero concentration gradient conditions at the inlet and outlet boundaries that provide a wide number of options. Arbitrary initial solute concentration distributions throughout the media can be considered via explicit formulations or numerical integration. The analytical solutions presented have been verified against numerical solutions from a finite‐element‐based approach and an existing closed‐form solution for double‐layered media with an excellent correlation being found in both cases. A practical application pertaining to advective transport induced by consolidation of underlying sediment layers on contaminant movement within a capped contaminated sediment system is presented. Comparison of the calculated concentrations and fluxes with alternative approaches clearly illustrates the need to consider advection processes. Consideration of the different features of contaminant transport due to varying pore‐water velocity fields in primary consolidation and secondary consolidation stages is achieved via the use of non‐uniform initial concentration distributions within the proposed analytical solutions. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

电离层氧离子83.4 nm辐射计算方法          下载免费PDF全文

刘鑫宇  张效信  何飞  陈波 《地球物理学报》2017,60(9):3308-3314

氧离子83.4 nm辐射是由氧离子辐射跃迁产生的,是电离层极紫外日辉辐射中辐射强度较高的信号之一.从空间对其进行成像为高层大气状态的监测提供了一种强有力的方法.为了准确的描述辐射强度的分布情况,本文在MSISE-00大气模型下,用AURIC计算氧离子83.4 nm辐射的初始体辐射率、电离层氮气分子、氧气分子以及氧原子的密度分布,接着,用Chapman函数生成氧离子密度分布,计算共振散射作用下的体辐射率.然后,给出在不同的初始辐射率情况下,沿天底方向观测的辐射强度对比.最后,与Anderson的计算结果作了两组对比,指出由电子碰撞产生的初始体辐射率占比提高16%,总的辐射强度会提高30%.本文的工作为低热层大气氧离子密度和光电子通量的探测提供支持,这对电离层电子密度反演具有理论意义.  相似文献   

Efficient DEM‐based overland flow routing using integrated recursive algorithms          下载免费PDF全文

Pin‐Chun Huang  Kwan Tun Lee 《水文研究》2017,31(5):1007-1017

Two primary concerns in performing watershed overland flow routing are the numerical instability and computational efficiency. The stability of executing an explicit scheme has to be maintained by observing the Courant–Friedrich–Lewy criterion, which is adopted to confirm that the numerical marching speed is larger than the wave celerity. Moreover, there is another criterion of time step devised in previous studies to avoid back‐and‐forth refluxing between adjacent grids. The situation of refluxing usually occurs on flat regions. In light of this, the selection of a small time increment to honor both restrictions simultaneously is believed to decrease the computational efficiency in performing overland flow routing. This study aims at creating a robust algorithm to relax both restrictions. The proposed algorithm was first implemented on a one‐dimensional overland plane to evaluate the accuracy of the numerical result by comparing it with an analytical solution. Then, the algorithm was further applied to a watershed for 2D runoff simulations. The results show that the proposed integrated algorithm can provide an accurate runoff simulation and achieve satisfactory performance in terms of computational speed.  相似文献   

Brief history of ground-based very high energy gamma-ray astrophysics with atmospheric air Cherenkov telescopes     

《Astroparticle Physics》2014

The discovery of the Crab Nebula as the first source of TeV gamma rays in 1989, using the technique of ground-based imaging air Cherenkov telescope, has marked the birthday of observational gamma astronomy in very high energy range. The team led by Trevor Weekes, after twenty years of trial and error, success and misfortune, step-by-step improvements in both the technique and understanding of gamma shower discrimination methods, used the 10 m diameter telescope on Mount Hopkins in Arizona, and succeeded measuring a 9σ signal from the direction of Crab Nebula. As of today over 160 sources of gamma rays of very different types, of both galactic and extra-galactic origin, have been discovered due to this technique. This is a really fast evolving branch in science, rapidly improving our understanding of the most violent and energetic sources and processes in the sky.The study of these sources provides clues to many basic questions in astrophysics, astro-particle physics, physics of cosmic rays and cosmology. Today’s telescopes, despite the young age of the technique, offer a solid performance. The technique is still maturing, leading to the next generation large instrument. This article is devoted to outlining the milestones in a long history that step-by-step have made this technique emerge and have brought about today’s successful source hunting.  相似文献   

Element spots in Ap and Hg‐Mn stars from current‐driven diffusion     

V. Urpin 《Astronomische Nachrichten》2015,336(3):266-270

The stars of the middle main sequence often have spot‐like chemical structures at their surfaces. We consider the diffusion process caused by electric currents that can lead to the formation of such chemical spots. Diffusion is considered using the partial momentum equations derived by the Chapman‐Enskog method. We argue that diffusion caused by electric currents can substantially change the surface chemistry of stars and form spotted chemical structures even in a relatively weak magnetic field. The considered mechanism can be responsible for a formation of element spots in Hg‐Mn and Ap‐stars. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Simulation and Validation of the Aerosol Optical Thicknessover China in 2006     

ZHANG Hu  ZHANG Min  CUI Zhenlei  WANG Yuesi  XIN Jinyuan 《Acta Meteorologica Sinica》2012,26(3):330-344

  相似文献